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Magmatic Differentiation at an Island-arc Caldera: Okmok Volcano, Aleutian Islands, Alaska
Okmok volcano is situated on oceanic crust in the central Aleutian arc and experienced large (~15 km3) caldera-forming eruptions at ~12 000 years bp and 2050 years bp. Each caldera-forming eruption began with a small Plinian rhyodacite event followed by the emplacement of a dominantly andesitic ash-flow unit, whereas effusive inter- and post-caldera lavas have been more basaltic. Phenocryst assemblages are composed of olivine + pyroxene + plagioclase ± Fe–Ti oxides and indicate crystallization at 1000–1100°C at 0·1–0·2 GPa in the presence of 0–4% H2O. The erupted products follow a tholeiitic evolutionary trend and calculated liquid compositions range from 52 to 68 wt % SiO2 with 0·8–3·3 wt % K2O. Major and trace element models suggest that the more evolved magmas were produced by 50–60% in situ fractional crystallization around the margins of the shallow magma chamber. Oxygen and strontium isotope data (18O 4·4–4·9, 87Sr/ 86Sr 0·7032–0·7034) indicate interaction with a hydrothermally altered crustal component, which led to elevated thorium isotope ratios in some caldera-forming magmas. This compromises the use of uranium–thorium disequilibria [(230Th/ 238U) = 0·849–0·964] to constrain the time scales of magma differentiation but instead suggests that the age of the hydrothermal system is ~100 ka. Modelling of the diffusion of strontium in plagioclase indicates that many evolved crystal rims formed less than 200 years prior to eruption. This addition of rim material probably reflects the remobilization of crystals from the chamber margins following replenishment. Basaltic recharge led to the expansion of the magma chamber, which was responsible for the most recent caldera-forming event.
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Petrogenesis of Ultramafic Rocks from the Ultrahigh-pressure Metamorphic Kimi Complex in Eastern Rhodope (NE Greece)
Widespread bodies of garnet–spinel metaperidotites with pyroxenitic layers occur in the ultrahigh-pressure metamorphic Kimi Complex. In this study we address the origin of such peridotite–pyroxenite associations in the context of polybaric melting regimes. We conduct a detailed geochemical investigation of major and trace element relations and compare them with a range of major element modelling scenarios. With increasing bulk-rock MgO content, the garnet–spinel metaperidotites exhibit decreasing CaO, Al2O3, TiO2, and Na2O along with increasing Ni and a gradually increasing Zr/Zr* anomaly, consistent with an origin as residues after variable degrees of melt extraction. The major element modelling further suggests a polybaric adiabatic decompression melting regime beginning at high to ultrahigh pressure, with an intermediate character between pure batch and fractional melting and a mean extent of melting of 9–11%. The pyroxenites exhibit major element compositions that cannot be reproduced by experimental or calculated melts of peridotite. Moreover, the Kimi pyroxenites have highly variable Ni and Sc contents and a wide range of Mg-number (0· 76–0· 89), inconsistent with an origin as frozen melts or the products of melt–peridotite interaction. However, both the major element systematics and the observed rare earth element patterns, with both convex and concave shapes, can be explained by an origin as clinopyroxene-rich, high-pressure cumulates involving garnet and/or Cr-spinel.
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Origin of Pyroxenite-Peridotite Veined Mantle by Refertilization Reactions: Evidence from the Ronda Peridotite (Southern Spain)
The Ronda orogenic peridotite (southern Spain) contains a variety of pyroxene-rich rocks ranging from high-pressure garnet granulites and pyroxenites to low-pressure plagioclase–spinel websterites. The ‘asthenospherized’ part of the Ronda peridotite contains abundant layered websterites (‘group C’ pyroxenites), without significant deformation, that occur as swarms of layers showing gradual modal transitions towards their host peridotites. Previous studies have suggested that these layered pyroxenites formed by the replacement of refractory spinel peridotites. Here, we present a major- and trace-element, and numerical modelling study of a layered outcrop of group C pyroxenite near the locality of Tolox aimed at constraining the origin of these pyroxenites after host peridotites by pervasive pyroxene-producing, refertilization melt–rock reactions. Mg-number [= Mg/(Mg + Fe) cationic ratio] numerical modelling shows that decreasing Mg-number with increasing pyroxene proportion, characteristic of Ronda group C pyroxenites, can be accounted for by a melt-consuming reaction resulting in the formation of mildly evolved, relatively low Mg-number melts (~0·65) provided that the melt fraction during reaction and the time-integrated melt/rock ratio are high enough (>0·1 and > 1, respectively) to balance Mg–Fe buffering by peridotite minerals. This implies strong melt focusing caused by melt channelling in high-porosity domains resulting from compaction processes in a partial melted lithospheric domain below a solidus isotherm represented by the Ronda peridotite recrystallization front. The chondrite-normalized rare earth element (REE) patterns of group C whole-rocks and clinopyroxenes are convex-upward. Numerical modeling of REE variations in clinopyroxene produced by a pyroxene-forming, melt-consuming reaction results in curved trajectories in the (Ce/Nd)N vs (Sm/Yb)N diagram (where N indicates chondrite normalized). Based on (Ce/Nd)N values, two transient, enriched domains between the light REE (LREE)-depleted composition of the initial peridotite and that of the infiltrated melt may be distinguished in the reaction column: (1) a lower domain characterized by convex-upward REE patterns similar to those observed in Ronda group C pyroxenite–peridotite; (2) an upper domain characterized by melts with strongly LREE-enriched compositions. The latter are probably volatile-rich, small-volume melt fractions residual after the refertilization reactions that generated group C pyroxenites, which migrated throughout the massif—including the unmelted lithospheric spinel-tectonite domain. The Ronda mantle domains affected by pyroxenite- and dunite- or harzburgite-forming reactions (the ‘layered granular’ subdomain and ‘plagioclase-tectonite’ domain) are on average more fertile than the residual, ‘coarse granular’ subdomain at the recrystallization front. This indicates that refertilization traces the moving boundaries of receding cooling of a thinned and partially melted subcontinental lithosphere. This refertilization process may be widespread during transient thinning and melting of depleted subcontinental lithospheric mantle above upwelling asthenospheric mantle.
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